Explanation
To identify the correct option with the same empirical formula for both compounds, we need to understand what an empirical formula is. An empirical formula represents the simplest whole-number ratio of the atoms in a compound. Let's analyze each option to determine if the compounds share the same empirical formula.
(Option D) C6H12O6 & CH3COOH:
C6H12O6 (Glucose): The molecular formula is C6H12O6.
The ratio of carbon (C) to hydrogen (H) to oxygen (O) is 6:12:6, which simplifies to 1:2:1.
The empirical formula is CH2O.
CH3COOH (Acetic Acid): The molecular formula is CH3COOH.
The ratio of carbon (C) to hydrogen (H) to oxygen (O) is 2:4:2, which simplifies to 1:2:1.
The empirical formula is also CH2O.
Conclusion: The empirical formulas are the same (CH2O).
(Option A) H2O & H2O2:
H2O (Water): The molecular formula is H2O.
The ratio of hydrogen (H) to oxygen (O) is 2:1.
The empirical formula is H2O, as it's already in the simplest ratio.
H2O2 (Hydrogen Peroxide): The molecular formula is H2O2.
The ratio of hydrogen (H) to oxygen (O) is 2:2, which simplifies to 1:1.
The empirical formula is HO.
Conclusion: The empirical formulas are different (H2O vs. HO).
(Option B) C6H12 & C6H6:
C6H12 (Hexane): The molecular formula is C6H12.
The ratio of carbon (C) to hydrogen (H) is 6:12, which simplifies to 1:2.
The empirical formula is CH2.
C6H6 (Benzene): The molecular formula is C6H6.
The ratio of carbon (C) to hydrogen (H) is 6:6, which simplifies to 1:1.
The empirical formula is CH.
Conclusion: The empirical formulas are different (CH2 vs. CH).
(Option C) H2S2O3 & H2SO4:
H2S2O3 (Thiosulfuric Acid): The molecular formula is H2S2O3.
The ratio of hydrogen (H) to sulfur (S) to oxygen (O) is 2:2:3.
The empirical formula is H2S2O3, which cannot be simplified further.
H2SO4 (Sulfuric Acid): The molecular formula is H2SO4.
The ratio of hydrogen (H) to sulfur (S) to oxygen (O) is 2:1:4.
The empirical formula is H2SO4, which cannot be simplified further.
Conclusion: The empirical formulas are different (H2S2O3 vs. H2SO4).
Subject: Chemistry
Topic: Intro to Fundamental Concepts of Chemistry
Subtopic :Basic Concepts/ Empirical Formula
Difficulty Level: Hard
Option |
Compounds |
Molecular Formula |
Empirical Formula |
Simplification Steps |
A |
Water |
H2O |
H2O |
Already in simplest ratio |
|
Hydrogen Peroxide |
H2O2 |
HO |
H2O2 -> (H
= 2:2) -> HO |
B |
Hexane |
C6H12 |
CH2 |
C6H12 -> (C
= 6:12) -> CH2 |
|
Benzene |
C6H6 |
CH |
C6H6 -> (C
= 6:6) -> CH |
C |
Thiosulfuric Acid |
H2S2O3 |
H2S2O3 |
Cannot be simplified further |
|
Sulfuric Acid |
H2SO4 |
H2SO4 |
Cannot be simplified further |
D |
Glucose |
C6H12O6 |
CH2O |
C6H12O6 -> (C:H
= 6:12:6) -> CH2O |
|
Acetic Acid |
CH3COOH |
CH2O |
CH3COOH -> (C:H
= 2:4:2) -> CH2O |
Flow chart for a substance containing elements A and X